Organometallic isocyanides of the general formula o-([M]CH2)C6H4NC ([M] = CpMo(CO)3, CpW(CO)3 (Cp = eta5-C6H5), Mn(CO)5) were prepared by reaction of o-(ICH2)C6H4NC with the corresponding metal carbonyl anion.
o-Isocyanobenzyl complexes of transition metals as novel organometallic isocyanide ligands, (.eta.5-C5H5)M(CO)3(o-CH2C6H4NC) (M = Mo, W) and Mn(CO)5(o-CH2C6H4NC). Synthesis and reactivity toward palladium(II) and platinum(II) substrates
MICHELIN, RINO
1984
Abstract
Organometallic isocyanides of the general formula o-([M]CH2)C6H4NC ([M] = CpMo(CO)3, CpW(CO)3 (Cp = eta5-C6H5), Mn(CO)5) were prepared by reaction of o-(ICH2)C6H4NC with the corresponding metal carbonyl anion.File in questo prodotto:
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