The paper reports the development of a mathematical model which has been applied to the polymerization of styrene initiated by iodine in ethylene dichloride solution. Our previous work on the system concluded for a pseudocationic mechanism based on the admission of non-ionic propagating species. The computer analysis performed using the mathematical model allowed us to derive theoretical conversion-and conductivity-time curves which perfectly reproduce the experimental shapes under different conditions. The agreement between the theoretical and experimental results demonstrates that the reaction mechanism previously formulated and the mathematical treatment proposed are correct.
Modelling of polymerization reactions : 2. Computer simulation of iodine initiated polymerization of styrene
MASCHIO, GIUSEPPE;
1982
Abstract
The paper reports the development of a mathematical model which has been applied to the polymerization of styrene initiated by iodine in ethylene dichloride solution. Our previous work on the system concluded for a pseudocationic mechanism based on the admission of non-ionic propagating species. The computer analysis performed using the mathematical model allowed us to derive theoretical conversion-and conductivity-time curves which perfectly reproduce the experimental shapes under different conditions. The agreement between the theoretical and experimental results demonstrates that the reaction mechanism previously formulated and the mathematical treatment proposed are correct.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
