The ESIMS technique, combined with H-1 NMR evidence, provides a precise inventory of the catalytic Ti-IV precursors and the characterization of the reactive peroxometal complex involved in enantioselective sulfoxidation employing the Ti-IV-homochiral trialkanolamine-alkylhydroperoxide system.
Use of electrospray ionization mass spectrometry to characterize chiral reactive intermediates in a titanium alkoxide mediated sulfoxidation reaction
BONCHIO, MARCELLA;LICINI, GIULIA MARINA;MORO, STEFANO;
1997
Abstract
The ESIMS technique, combined with H-1 NMR evidence, provides a precise inventory of the catalytic Ti-IV precursors and the characterization of the reactive peroxometal complex involved in enantioselective sulfoxidation employing the Ti-IV-homochiral trialkanolamine-alkylhydroperoxide system.File in questo prodotto:
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