The 1,1′-binaphthalene derivative 1 is the first acetylene equivalent developed for asymmetric Diels–Alder reactions. It reacts at room temperature with a variety of unsymmetric dienes in a nearly stereospecific fashion. The initial adducts can be cleaved with sodium amalgam to give products corresponding to those formally obtained by acetylene addition to dienes.
Ethylenebis(sulfonyl)-bridged 1,1'-binaphthalene, An Atropisomeric Dienophile For Highly Diastereoselective Diels-alder Reactions
LICINI, GIULIA MARINA
1989
Abstract
The 1,1′-binaphthalene derivative 1 is the first acetylene equivalent developed for asymmetric Diels–Alder reactions. It reacts at room temperature with a variety of unsymmetric dienes in a nearly stereospecific fashion. The initial adducts can be cleaved with sodium amalgam to give products corresponding to those formally obtained by acetylene addition to dienes.File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
