The electronic structure of the cyclic dipeptide of dehydrophenylalanine has been investigated by vapour-phase He(I) and He(II) UV photoelectron spectroscopy. Assignments are proposed by comparison with related molecules and supported by INDO/S calculations. Analogies and differences with respect to the photoelectron results of the cyclic dipeptide of dehydroalanine and corresponding acyclic compounds are discussed. © 1986.
Conformational and Electronic Effects In Dehydroaminoacid Derivatives
CASARIN, MAURIZIO;
1986
Abstract
The electronic structure of the cyclic dipeptide of dehydrophenylalanine has been investigated by vapour-phase He(I) and He(II) UV photoelectron spectroscopy. Assignments are proposed by comparison with related molecules and supported by INDO/S calculations. Analogies and differences with respect to the photoelectron results of the cyclic dipeptide of dehydroalanine and corresponding acyclic compounds are discussed. © 1986.
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