In the homobimetallic complexes anti-{2,7-dimethyl-as-indacene-diide-[M(COD)](2)}(M = Rh, Lr),a quite unusual COD group orientation may be induced by the presence of pi-hydrogen bonds between olefinic protons of COD and the pi-electron cloud of the six-membered ring of the bridging ligand.
Anti-{2,7-dimethyl-as-indacene-diide-[M(COD)]2} complexes (M=Rh(I), Ir(I)). Molecular conformations assisted by C–H···arene intramolecular π-hydrogen bonds
CECCON, ALBERTO;SANTI, SAVERIO;
1998
Abstract
In the homobimetallic complexes anti-{2,7-dimethyl-as-indacene-diide-[M(COD)](2)}(M = Rh, Lr),a quite unusual COD group orientation may be induced by the presence of pi-hydrogen bonds between olefinic protons of COD and the pi-electron cloud of the six-membered ring of the bridging ligand.
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