In the homobimetallic complexes anti-{2,7-dimethyl-as-indacene-diide-[M(COD)](2)}(M = Rh, Lr),a quite unusual COD group orientation may be induced by the presence of pi-hydrogen bonds between olefinic protons of COD and the pi-electron cloud of the six-membered ring of the bridging ligand.
Titolo: | Anti-{2,7-dimethyl-as-indacene-diide-[M(COD)]2} complexes (M=Rh(I), Ir(I)). Molecular conformations assisted by C–H···arene intramolecular π-hydrogen bonds | |
Autori: | ||
Data di pubblicazione: | 1998 | |
Rivista: | ||
Abstract: | In the homobimetallic complexes anti-{2,7-dimethyl-as-indacene-diide-[M(COD)](2)}(M = Rh, Lr),a quite unusual COD group orientation may be induced by the presence of pi-hydrogen bonds between olefinic protons of COD and the pi-electron cloud of the six-membered ring of the bridging ligand. | |
Handle: | http://hdl.handle.net/11577/2501497 | |
Appare nelle tipologie: | 01.01 - Articolo in rivista |
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