Anti-{2,7-dimethyl-as-indacene-diide-[M(COD)]2} complexes (M=Rh(I), Ir(I)). Molecular conformations assisted by C–H···arene intramolecular π-hydrogen bonds

Paolo, Ganis; Ceccon, Alberto; Thomas, Köhler; Francesco, Manoli; Santi, Saverio; Alfonso, Venzo

doi:10.1016/S1387-7003(98)00004-5

In the homobimetallic complexes anti-{2,7-dimethyl-as-indacene-diide-[M(COD)](2)}(M = Rh, Lr),a quite unusual COD group orientation may be induced by the presence of pi-hydrogen bonds between olefinic protons of COD and the pi-electron cloud of the six-membered ring of the bridging ligand.

Titolo:	Anti-{2,7-dimethyl-as-indacene-diide-[M(COD)]2} complexes (M=Rh(I), Ir(I)). Molecular conformations assisted by C–H···arene intramolecular π-hydrogen bonds
Autori:	Paolo Ganis CECCON, ALBERTO Thomas Köhler Francesco Manoli SANTI, SAVERIO Alfonso Venzo mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	1998
Rivista:	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Abstract:	In the homobimetallic complexes anti-{2,7-dimethyl-as-indacene-diide-[M(COD)](2)}(M = Rh, Lr),a quite unusual COD group orientation may be induced by the presence of pi-hydrogen bonds between olefinic protons of COD and the pi-electron cloud of the six-membered ring of the bridging ligand.
Handle:	http://hdl.handle.net/11577/2501497
Appare nelle tipologie:	01.01 - Articolo in rivista

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