The HOMO nature of RuRu bonds in triangulo-Ru3(CO)12 has been evidentiated by He(I) photo-electron spectroscopy and CNDO calculations. The bonding features of the three membered ring are compared to Walsh's picture of the 'isoelectronic' ring of cyclopropane. Both 4d and 5s5p orbitals are significantly involved in the RuRu bonds. © 1979.
Nature of the metal-meal bond in triangulo -Ru3(CO)12 from UVphotoelectro spectroscopy and quantum mechanical calculations
GRANOZZI, GAETANO;TONDELLO, EUGENIO;
1979
Abstract
The HOMO nature of RuRu bonds in triangulo-Ru3(CO)12 has been evidentiated by He(I) photo-electron spectroscopy and CNDO calculations. The bonding features of the three membered ring are compared to Walsh's picture of the 'isoelectronic' ring of cyclopropane. Both 4d and 5s5p orbitals are significantly involved in the RuRu bonds. © 1979.
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