A system of monosized hard spheres is studied to elucidate the nature of entropic depletion forces. Our calculations include effective forces between two spheres, a hard sphere and a wall, and the behavior near a step edge and a corner. Qualitative differences between our results and those of the Asakura-Oosawa theory are found. We also demonstrate the nonadditivity of such entropic forces in a simple example.
Depletion forces in hard-sphere colloids
MARITAN, AMOS;
1999
Abstract
A system of monosized hard spheres is studied to elucidate the nature of entropic depletion forces. Our calculations include effective forces between two spheres, a hard sphere and a wall, and the behavior near a step edge and a corner. Qualitative differences between our results and those of the Asakura-Oosawa theory are found. We also demonstrate the nonadditivity of such entropic forces in a simple example.File in questo prodotto:
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