Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti pre-catalyst. The alcohol coordination has a twofold action: it switches the Ti peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.
Non-covalent Activation of a Titanium(IV) Oxygen-Transfer Catalyst
ZONTA, CRISTIANO;LICINI, GIULIA MARINA
2013
Abstract
Kinetic studies, in combination with theoretical calculations, support a mechanism in which the coordination of one alcohol molecule activates a Ti pre-catalyst. The alcohol coordination has a twofold action: it switches the Ti peroxo complex to an active geometry, and it stabilises the reactive peroxo intermediate through hydrogen bonding.File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
