The Al-III-containing polyanions [Al-4(III)(H2O)(10)(beta-XW9O33H)(2)](4-) with X=As-III (1) and Sb-III (2) feature four aluminum(III) centers sandwiched by two trivacant (beta-XW9O33) Keggin units, and trigger peroxide catalysis as well as substrate coordination via multiple Lewis acid site interactions.

A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6− (X = AsIII, SbIII)

CARRARO, MAURO;SORARU', ANTONIO;BERARDI, SERENA;BONCHIO, MARCELLA
2013

Abstract

The Al-III-containing polyanions [Al-4(III)(H2O)(10)(beta-XW9O33H)(2)](4-) with X=As-III (1) and Sb-III (2) feature four aluminum(III) centers sandwiched by two trivacant (beta-XW9O33) Keggin units, and trigger peroxide catalysis as well as substrate coordination via multiple Lewis acid site interactions.
2013
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/2805738
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