Cu2+ coordination by a tridentate phenanthroline-related derivative (P120) was examined and compared to phenanthroline. Results from X-ray analysis underlined significant increments in the N-Cu bond lengths in Cu(P120)(H2O)SO4 which are counterbalanced by a closer approach of the apical oxygen donors to the metal. These modifications may be related to the different properties observed in physiological environment.
Biologically relevant Cu2+ complexes with a tridentate phenanthroline analogue: structural properties and DNA damage
MORELLATO, NICOLO';MUSETTI, CATERINA;PALUMBO, MANLIO;DOLMELLA, ALESSANDRO;BOLZATI, CRISTINA;SISSI, CLAUDIA
2015
Abstract
Cu2+ coordination by a tridentate phenanthroline-related derivative (P120) was examined and compared to phenanthroline. Results from X-ray analysis underlined significant increments in the N-Cu bond lengths in Cu(P120)(H2O)SO4 which are counterbalanced by a closer approach of the apical oxygen donors to the metal. These modifications may be related to the different properties observed in physiological environment.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
