A rigid octacationic tetraviologen-based cyclophane, TVBox(8+), is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 angstrom and width of 6.1 angstrom and is capable of encapsulating either two small pi-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50] crown-14.

Formation of ring-in-ring complexes between crown ethers and rigid TVBox8+

FRASCONI, MARCO;
2015

Abstract

A rigid octacationic tetraviologen-based cyclophane, TVBox(8+), is reported. It possesses a highly electron-deficient rectangular cavity with a length of 23 angstrom and width of 6.1 angstrom and is capable of encapsulating either two small pi-aromatic guest molecules, such as PhMe and PhCl, simultaneously, or one large molecule, e.g., bis-1,5-dinaphtho[50] crown-14.
2015
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3207753
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