Hafnium oxide doped silica films with ordered mesostructures were produced with hafnium:silicon ratios between 1:60 and 1:6. A surfactant–hafnium alkoxide complex was synthesized and used as a template in a sol–gel dip-coating process. Face-centred orthorhombic, 2D centred rectangular and lamellar films were formed by evaporation-induced self-assembly (EISA). The influence of subsequent heat treatment was studied by GISAXS and TEM. The surface and in-depth molecular composition of the films was studied by XPS.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
Hafnium Oxide Doped Mesostructured Silica Films
GROSS, SILVIA;
2007
Abstract
Hafnium oxide doped silica films with ordered mesostructures were produced with hafnium:silicon ratios between 1:60 and 1:6. A surfactant–hafnium alkoxide complex was synthesized and used as a template in a sol–gel dip-coating process. Face-centred orthorhombic, 2D centred rectangular and lamellar films were formed by evaporation-induced self-assembly (EISA). The influence of subsequent heat treatment was studied by GISAXS and TEM. The surface and in-depth molecular composition of the films was studied by XPS.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.