DMSO promotes dimensional variability driving the formation of Cu-bpy architectures such as a 3D nanoporous network (1) and a 1D chiral polymer (2) self-assembled from achiral building blocks. The same solvent rules a reversible conversion between 1 and 2.
Exploiting dimensional variability in coordination polymers: Solvent promotes reversible conversion between 3D and chiral 1D architectures
Rancan, Marzio;Armelao, Lidia
2015
Abstract
DMSO promotes dimensional variability driving the formation of Cu-bpy architectures such as a 3D nanoporous network (1) and a 1D chiral polymer (2) self-assembled from achiral building blocks. The same solvent rules a reversible conversion between 1 and 2.
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