This paper describes the preparation and the photoelectrochemical performances of visible light driven photoanodes based on novel r-GO/-Cu2V2O7/TiO2 nanorods/composites. -Cu2V2O7 was deposited on both fluorine doped tin oxide (FTO) and TiO2 nanorods (NRs)/FTO by a fast and convenient Aerosol Assisted Spray Pyrolysis (AASP) procedure. Ethylenediamine (EN), ammonia and citric acid (CA) were tested as ligands for Cu2+ ions in the aerosol precursors solution. The best-performing deposits, in terms of photocurrent density, were obtained when NH3 was used as ligand. When -Cu2V2O7 was deposited on the TiO2 NRs a good improvement in the durability of the photoanode was obtained, compared with pure -Cu2V2O7 on FTO. A further remarkable improvement in durability and photocurrent density was obtained upon addition, by electrophoretic deposition, of reduced graphene oxide (r-GO) flakes on the -Cu2V2O7/TiO2 composite material. The samples were characterized by X-ray Photoelectron Spectroscopy (XPS), Raman, High Resolution Transmission Electron Microscopy (HR-TEM), Scanning Electron Microscopy (SEM), Wide Angle X-ray Diffraction (WAXD) and UV–Vis spectroscopies. The photoelectrochemical (PEC) performances of -Cu2V2O7 on FTO, -Cu2V2O7/TiO2 and r-GO/-Cu2V2O7/TiO2 were tested in visible light by linear voltammetry and Electrochemical Impedance Spectroscopy (EIS) measurements.

Visible light driven photoanodes for water oxidation based on novel r-GO/β-Cu2V2O7/TiO2 nanorods composites

Girardi, Leonardo
Investigation
;
Rizzi, Gian Andrea
Writing – Original Draft Preparation
;
Sartorel, Andrea
Investigation
;
Marega, Carla
Investigation
;
Granozzi, Gaetano
Supervision
2018

Abstract

This paper describes the preparation and the photoelectrochemical performances of visible light driven photoanodes based on novel r-GO/-Cu2V2O7/TiO2 nanorods/composites. -Cu2V2O7 was deposited on both fluorine doped tin oxide (FTO) and TiO2 nanorods (NRs)/FTO by a fast and convenient Aerosol Assisted Spray Pyrolysis (AASP) procedure. Ethylenediamine (EN), ammonia and citric acid (CA) were tested as ligands for Cu2+ ions in the aerosol precursors solution. The best-performing deposits, in terms of photocurrent density, were obtained when NH3 was used as ligand. When -Cu2V2O7 was deposited on the TiO2 NRs a good improvement in the durability of the photoanode was obtained, compared with pure -Cu2V2O7 on FTO. A further remarkable improvement in durability and photocurrent density was obtained upon addition, by electrophoretic deposition, of reduced graphene oxide (r-GO) flakes on the -Cu2V2O7/TiO2 composite material. The samples were characterized by X-ray Photoelectron Spectroscopy (XPS), Raman, High Resolution Transmission Electron Microscopy (HR-TEM), Scanning Electron Microscopy (SEM), Wide Angle X-ray Diffraction (WAXD) and UV–Vis spectroscopies. The photoelectrochemical (PEC) performances of -Cu2V2O7 on FTO, -Cu2V2O7/TiO2 and r-GO/-Cu2V2O7/TiO2 were tested in visible light by linear voltammetry and Electrochemical Impedance Spectroscopy (EIS) measurements.
2018
File in questo prodotto:
File Dimensione Formato  
nanomaterials-08-00544-v2.pdf

accesso aperto

Tipologia: Postprint (accepted version)
Licenza: Accesso gratuito
Dimensione 6.6 MB
Formato Adobe PDF
6.6 MB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3283175
Citazioni
  • ???jsp.display-item.citation.pmc??? 2
  • Scopus 28
  • ???jsp.display-item.citation.isi??? 27
  • OpenAlex ND
social impact