hree metallacryptate supramolecular assemblies have been obtained using salicylhydroxamic acid derivatives. The periphery of the ligands has been designed to obtain interactions between the metallacryptate units. By the use of ligands which bear amino (NH2) or 4-pyridyl groups the units assemble into parallel chains and into a MOF-like structure, respectively. In both solids, a honeycomb porous structure is obtained.
Three-Dimensional Porous Architectures Based on Mn II/III Three-Blade Paddle Wheel Metallacryptates
SPIGOLON, GIULIA;Licini, Giulia;
2019
Abstract
hree metallacryptate supramolecular assemblies have been obtained using salicylhydroxamic acid derivatives. The periphery of the ligands has been designed to obtain interactions between the metallacryptate units. By the use of ligands which bear amino (NH2) or 4-pyridyl groups the units assemble into parallel chains and into a MOF-like structure, respectively. In both solids, a honeycomb porous structure is obtained.File in questo prodotto:
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