Membranes of polyamine (PA-SiNH2)m, containing silica reacted with 3-aminopropyltriethoxysilane (APTES) in hydrolytic conditions were prepared via solution casting, followed by methylation and ion exchange process. The influence of amino-functionalized silica (Si-NH2) on the properties of the obtained membrane was investigated. Fourier transform infrared spectroscopy (FTIR) and Nuclear magnetic resonance spectroscopy (NMR) were used to investigate the chemical features of the silica and its interaction with the polyamine polymer. The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of the modified membrane confirmed it is stable up to 300 °C. The thermal stability is the result of the interaction of modified silica particles and polyamine polymer. It was demonstrated that the performance of the (PA-SiNH2)m anion exchange membrane is greatly improved by incorporation of silica nanoparticles as compared with the anion exchange membrane (PK-PDAPm), which doesn't contain silica. Therefore, the (PA-SiNH2)m is a suitable candidate for electrochemical applications.
Properties of anion exchange membrane based on polyamine: Effect of functionalized silica particles prepared by sol–gel method
Vezzù, Keti;Di Noto, Vito;Cavinato, Gianni;
2018
Abstract
Membranes of polyamine (PA-SiNH2)m, containing silica reacted with 3-aminopropyltriethoxysilane (APTES) in hydrolytic conditions were prepared via solution casting, followed by methylation and ion exchange process. The influence of amino-functionalized silica (Si-NH2) on the properties of the obtained membrane was investigated. Fourier transform infrared spectroscopy (FTIR) and Nuclear magnetic resonance spectroscopy (NMR) were used to investigate the chemical features of the silica and its interaction with the polyamine polymer. The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) of the modified membrane confirmed it is stable up to 300 °C. The thermal stability is the result of the interaction of modified silica particles and polyamine polymer. It was demonstrated that the performance of the (PA-SiNH2)m anion exchange membrane is greatly improved by incorporation of silica nanoparticles as compared with the anion exchange membrane (PK-PDAPm), which doesn't contain silica. Therefore, the (PA-SiNH2)m is a suitable candidate for electrochemical applications.Pubblicazioni consigliate
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