A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.

Postsynthetic Metalated MOFs as Atomically Dispersed Catalysts for Hydroformylation Reactions

Tang P.;Paganelli S.;Carraro F.;Blanco M.;Marega C.;Badocco D.;Pastore P.;Doonan C. J.;Agnoli S.
2020

Abstract

A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
2020
Inglese
Inglese
ACS APPLIED MATERIALS & INTERFACES
12
49
54798
54805
8
American Chemical Society
Internazionale
anonymous
sì
33232111
WOS:000599505200052
2-s2.0-85097808684
W3108688908
Applied Physics/Condensed Matter/Materials Science encompasses the resources of three related disciplines: Applied Physics, Condensed Matter Physics, and Materials Science. The applied physics resources are concerned with the applications of topics in condensed matter as well as optics, vacuum science, lasers, electronics, cryogenics, magnets and magnetism, acoustical physics and mechanics. The condensed matter physics resources are concerned with the study of the structure and the thermal, mechanical, electrical, magnetic and optical properties of condensed matter. They include superconductivity, surfaces, interfaces, thin films, dielectrics, ferroelectrics and semiconductors. The materials science resources are concerned with the physics and chemistry of materials and include ceramics, composites, alloys, metals and metallurgy, nanotechnology, nuclear materials, adhesion and adhesives. Resources dealing with polymeric materials are listed in the Organic Chemistry/Polymer Science category.
heterogeneous catalysis; hydroformylation of olefins; metal-organic frameworks; rhodium coordination compounds; single-atom catalysts
https://pubs.acs.org/doi/abs/10.1021/acsami.0c17073
AUSTRALIA
reserved
Tang, P.; Paganelli, S.; Carraro, F.; Blanco, M.; Ricco, R.; Marega, C.; Badocco, D.; Pastore, P.; Doonan, C. J.; Agnoli, S.
01 CONTRIBUTO IN RIVISTA::01.01 - Articolo in rivista
info:eu-repo/semantics/article
10
262
01.01 - Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3364465
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