The solvent-assisted self-assembly of a blue-emitting neutral platinum(ii) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal⋯metal and π–π) interactions. © The Partner Organisations 2014.
Self-assembly of a neutral platinum(ii) complex into highly emitting microcrystalline fibers through metallophilic interactions
Aliprandi A.;
2014
Abstract
The solvent-assisted self-assembly of a blue-emitting neutral platinum(ii) complex into micrometer-long and highly crystalline fibers has been achieved. The aggregates show highly efficient (quantum yield up to 74%) polarized yellow-orange light emission, as a consequence of their high degree of supramolecular order imparted by weak non-covalent intermolecular (metal⋯metal and π–π) interactions. © The Partner Organisations 2014.File in questo prodotto:
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