The parity-violating energy distribution in the vicinity of the transition point of a symmetric chemical reaction path of a chiral molecule is discussed using the Hartree-Fock procedure. The stability of the sulfur enantiomer and chiral activated complex in the transition state was studied. The results showed that kinetic effects during chemical synthesis of chiral molecules was more stable with respect to the thermodynamical stability of the two-mirror image reaction products.
Parity-violating effects in asymmetric chemical reactions: A theoretical study on the CHFClBr molecule
Soncini A.;
2000
Abstract
The parity-violating energy distribution in the vicinity of the transition point of a symmetric chemical reaction path of a chiral molecule is discussed using the Hartree-Fock procedure. The stability of the sulfur enantiomer and chiral activated complex in the transition state was studied. The results showed that kinetic effects during chemical synthesis of chiral molecules was more stable with respect to the thermodynamical stability of the two-mirror image reaction products.File in questo prodotto:
Non ci sono file associati a questo prodotto.
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
