Mixtures of hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs) are suitable as drop-in substitutes in refrigeration and air conditioning, due to the low global warming potential (GWP) and desired thermodynamic properties. In the present work, the flow boiling heat transfer of four HFOs/HFCs mixtures has been studied inside a 0.96 mm diameter channel. Three of those mixtures, R513A (R1234yf/R134a, 56/44 % by mass, GWP100-y = 629), R516A (R1234yf/R152a/R134a 77.5/14/8.5 % by mass, GWP100-y = 131) and R515B (R1234ze(E)/R227ea, 91/9 % by mass, GWP100-y = 299), are azeotropic mixtures, while the fourth is quasiazeotropic mixture R450A (R1234ze(E)/R134a, 56/44 % by mass, GWP100-y = 547, ΔTGL = 0.63 K at 30 °C). The experimental campaign was conducted using a test section where the flow boiling is promoted by a secondary fluid, at 30 ◦C mean saturation temperature and mass flux between 300 kg m− 2 s− 1 and 600 kg m− 2 s− 1. The present data have been compared with the heat transfer coefficient of R134a, in order to assess the suitability of its drop-in substitutes. From the comparison between experimental data and the predictions from some semiempirical models, a modified method is presented. The new flow boiling heat transfer correlation has been successfully tested with data of propane, propylene, R32 and R1234yf.

Flow boiling heat transfer of new refrigerant blends: Experimental data in a microchannel and modelling

Azzolin, Marco;Berto, Arianna
;
Bortolin, Stefano;Del Col, Davide
2025

Abstract

Mixtures of hydrofluorocarbons (HFCs) and hydrofluoroolefins (HFOs) are suitable as drop-in substitutes in refrigeration and air conditioning, due to the low global warming potential (GWP) and desired thermodynamic properties. In the present work, the flow boiling heat transfer of four HFOs/HFCs mixtures has been studied inside a 0.96 mm diameter channel. Three of those mixtures, R513A (R1234yf/R134a, 56/44 % by mass, GWP100-y = 629), R516A (R1234yf/R152a/R134a 77.5/14/8.5 % by mass, GWP100-y = 131) and R515B (R1234ze(E)/R227ea, 91/9 % by mass, GWP100-y = 299), are azeotropic mixtures, while the fourth is quasiazeotropic mixture R450A (R1234ze(E)/R134a, 56/44 % by mass, GWP100-y = 547, ΔTGL = 0.63 K at 30 °C). The experimental campaign was conducted using a test section where the flow boiling is promoted by a secondary fluid, at 30 ◦C mean saturation temperature and mass flux between 300 kg m− 2 s− 1 and 600 kg m− 2 s− 1. The present data have been compared with the heat transfer coefficient of R134a, in order to assess the suitability of its drop-in substitutes. From the comparison between experimental data and the predictions from some semiempirical models, a modified method is presented. The new flow boiling heat transfer correlation has been successfully tested with data of propane, propylene, R32 and R1234yf.
2025
   Environmentally friendly high-glide refrigerant blends for high-temperature heat pumps and next-generation refrigerators
   GLIDE4HEAT
   MUR
   PNRR M4C2 Investimento 1.1 Progetto di Ricerca di Rilevante Interesse Nazionale (PRIN)
   C53D23001690006,
File in questo prodotto:
File Dimensione Formato  
IJHMT_164_2025_Flow boiling blends.pdf

accesso aperto

Tipologia: Published (Publisher's Version of Record)
Licenza: Creative commons
Dimensione 3.05 MB
Formato Adobe PDF
3.05 MB Adobe PDF Visualizza/Apri
Pubblicazioni consigliate

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11577/3556888
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 2
  • ???jsp.display-item.citation.isi??? 2
  • OpenAlex 2
social impact